I highly recommend all of these books.
Essential ActionScript 3.0 – Colin Moock
Head First PHP & MySQL - 
Programming Flex 3 – Chafic Kazoun and Joey Lott
Adobe Flex 3 Training from the Source - Jeff Tapper, Michael Labriola, Matthew Boles, James Talbot
PHP 6 and MySQL 5 for Dynamic Web Sites: Visual QuickPro Guide - Larry Ullman
Scott Kelby’s 7-Point System for Adobe Photoshop CS3
The Adobe Photoshop CS4 Book for Digital Photographers – Scott Kelby
The Adobe Photoshop Lightroom 2 Book for Digital Photographers
Presentation Zen: Simple Ideas on Presentation Design and Delivery – Garr Reynolds
UPDATE:
I have to add another book to the list. This one was written by two very good friends of mine: Greg Rewis and Stephanie Sullivan. Though I haven’t read it yet because they haven’t sent me a copy (*ahem*) I know it has to be an excellent resource for anyone working with CSS. Greg taught me almost everything I know about Evangelism as he and I have traveled all over the world together since 2000 talking about Dreamweaver, Flash, AIR, and other Macromedia/Adobe tools. He knows more about Dreamweaver than anybody I know. Stef is an expert in all things CSS, HTML, web standards, etc.
Thanks Mike – very helpful!
Hey, Mike – noticed you didn’t mention MY book… ;-)
@greg rewis: D’OH! Sorry, man. If you had sent me a copy it might have reminded me to recommend it. ;-)
The post has now been updated.
Mike, I heartily agree with you on “Learning ActionScript 3.0.” Without a doubt the best ActionScript book I’ve ever read. Essential ActionScript 3 made my head hurt. But I’ll get there. Thanks. I’m going to check out the rest of these books as I learn more.
I think it will be really helpful for me.
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What i think is this is a good listing and will be helpful.
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A great list of books, some which I had not heard of and will have to take a look at. I particulary enjoyed reading Presentation Zen, some really inspiring ideas in there and well worth reading.
Thanks for your info. very helpful.